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#ligand field

Every note tagged #ligand field, newest first — or browse the full archive.

September 1, 2026 Chemistry understanding

How a brushed glaze becomes glass

A brushed glaze is an aqueous mineral suspension that a kiln turns into a silicate melt and then into a frozen glass. Color and studio texture are properties of the optical species and of how far that melt equilibrates before it freezes.

#chemistry#glaze#glass#color#chromophores#ligand field
July 4, 2026 Chemistry

The colors on the palette are energy-level gaps: engineering pigments for permanence

A tube of paint is an electronic-structure problem plus a scattering problem, perceived by an eye. This post builds the mechanism-first taxonomy of color — conjugated π-systems, ligand-field d–d transitions, charge transfer, and semiconductor band gaps — leading with the modern synthetic pigments engineered to fix the lightfastness failures of their historic ancestors, then puts absorption and scattering back together with Kubelka–Munk.

#pigments#color#chromophores#lightfastness#charge transfer#ligand field#band gap#conjugation#Kubelka-Munk
pj Peter V. Johnston

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